Entertainment Shocking A-List Splits By Glamour 20 Sep 2016 It seemed to be happily ever after - until these celebrity relationships hit the rocks We can't get our head around this. Angelina Jolie has reportedly filed for divorce from Brad Pitt after twelve years together. It was reported that the actress, who first met husband Brad Pitt when filming Mr and Mrs Smith in 2004, has filed for divorce citing irreconcilable differences. Angelina has apparently asked for custody over the couple's six children, but is asking that Brad have visitation rights. The pair have been together for twelve years but married for two. Love is dead. But we thought they were for reals this time! We guess Katy Perry and John Mayer were just never meant to be. Sad face. After spending Christmas together, attending Obama’s second inauguration and even hinting at marriage, the pop stars have parted ways for a second time. This is a shocking split by default, purely because they were a pretty shocking couple to begin with. We would never have paired Game Of Thrones actress Emilia Clarke with Family Guy creator Seth MacFarlane. And neither would they, apparently. According to reports, the “distance” between them eventually took its toll, and they split after a relatively short six-month romance. Russell Crowe is rumoured to have split with Danielle Spencer, his wife of nine years, due to his heavy work schedule. The break-up is amicable but the split is surprising because they were considered one of Hollywood's strongest couples.